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Obituary
Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Communication | Regular issue | Vol 23, No. 8, 1985, pp.1915-1919
Published online, 1st January, 1970■ Synthesis of Carbaoenems with a RXCH2-Substituent in the 3-Position
Published online, 1st January, 1970
DOI: 10.3987/R-1985-08-1915
■ Synthesis of Carbaoenems with a RXCH2-Substituent in the 3-Position
Johannes G. de Vries,* Gerhard Sigmund, and Georg Vorisek
*Sandoz Forschungsinstitut, 1235 Wien, Brunnerstraße 59, Austria
Abstract
Carbapenems 6 were prepared by reacting mercaptans with bromoketone 3 followed by a Wittig sequence, or better through advanced intermediate 9. The carbapenem carboxylateas were chemically unstable; stability was not improved by changing the oxidation state of sulfur.
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