Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact: purchase@heterocycles.com

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Communication | Regular issue | Vol 23, No. 8, 1985, pp.1893-1896
Published online, 1st January, 1970
DOI: 10.3987/R-1985-08-1893
The Revised Structure of the Thermal Rearrangement Product of 4-Benzylideneamino-3-methyl-5-styrylisoxazole

Andreina Corsico Coda, Giovanni Desimoni,* and Alessandro Coda

*Dipartamento di Chimica Organica, Università di Pavia, V. le Taramelli 10, 27100 Pavia, Italy

Abstract

It had been claimed that the thermal rearrangement of 4-benzylideneamino-3-methyl-5-styrylisoxazol gave an isoxazolo-pyridine. This product was reinvestigated and shown to be 4-cinnamoyl-5-methyl-2-phenylimidazole, confirmed by X-ray analysis. A mechanism of formation is here proposed, involving the cleavage of the isoxazole N-O bond.