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Obituary
Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Communication | Regular issue | Vol 23, No. 8, 1985, pp.1889-1892
Published online, 1st January, 1970■ Synthetic Studies on Carbapenem Antibiotics from Penicillins. V. A Stereospecific Preparation of 4-Allylazetidinones
Published online, 1st January, 1970
DOI: 10.3987/R-1985-08-1889
■ Synthetic Studies on Carbapenem Antibiotics from Penicillins. V. A Stereospecific Preparation of 4-Allylazetidinones
Matsuhiko Aratani, Hideo Hirai, Kozo Sawada, and Masashi Hashimoto*
*Fujisawa Pharmaceutical Co. Ltd., 2-1-6 Kashima, Yodogawa-ku, Osaka 532, Japan
Abstract
A stereospecific preparation of chiral 4-allylazetidinones 3, key intermediates for the synthesis of the carbapenem antibiotics, has been achieved in good yields by reaction of 4-acetoxyazetidinones 2 with allylsilanes in the apresence of TMSOTf.
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