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Communication | Regular issue | Vol 23, No. 8, 1985, pp.1885-1888
Published online, 1st January, 1970
DOI: 10.3987/R-1985-08-1885
Synthesis of Vinca Alkaloids and Related Compounds XXIV. A New Rearrangement of the Isoquinuclidine Skeleton

Csaba Szántay,* Tibor Keve, Hedvig Bölcskei, Gábor Megyeri, and Eszter Gács-Baitz

*Central Research Institute for Chemistry, Hungarian Academy of Sciences, H-1025 Budapest, Pusztaszeri ut 59-67, P.O.Box 17, Hungary


A new rearrangement of the isoquinuclidine skeleton under solvolytic conditions was observed. A pentacyclic intermediate was isolated and its structure elucidated.