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Report | Regular issue | Vol 23, No. 7, 1985, pp.1707-1722
Published online, 1st January, 1970
DOI: 10.3987/R-1985-07-1707
13C NMR Spectra and Stereochemical Analysis of Piperidine Derived α-Aminonitriles

Reija Jokela, Tarja Tamminen, and Mauri Lounasmaa*

*Laboratory of Organic Chemistry, Helsinki University of Technology, P.O. Box 6100,FIN-02015 HUT, Espoo, Finland

Abstract

Carbon-13 NMR spectra of several α-aminonitriles are reported, along with their preparation via the mdified Polonovski reaction or the reductive cyanation of Fry. The subtituent effects for the cyano group in the different nitrogen heterocycles were determined and stereochemical conclusions are made.