Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact:

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Report | Regular issue | Vol 23, No. 3, 1985, pp.633-639
Published online, 1st January, 1970
DOI: 10.3987/R-1985-03-0633
Synthesis of α-Hydroxydimethylacetals from Nitrogen Heterocyclic Ketones Using Hypervalent Iodine Oxidation

Robert M. Moriarty,* Om Prakash, Cyriac T. Thachet, and Hikmat A. Musallam

*Department of Chemistry, University of Illinois at Chicago, 845 West Taylor St., Chicago, IL 60607-7061, U.S.A.


The synthesis of various α-hydroxydimethylacetals (2a-2j) has been achieved by the oxidation of nitrogen containing heterocyclic ketones (1a-1j) using C6H5I(OAc)2-KOH-MeOH . The nmr and mass spectra of the acetals are discussed.