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Obituary
Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Report | Regular issue | Vol 23, No. 3, 1985, pp.603-609
Published online, 1st January, 1970■ Reaction of 4-Bromoalkyl-4-methoxy-2,5-oxazolidione with Alcohol or α-Amino Acid Ester and Transformation of the Products
Published online, 1st January, 1970
DOI: 10.3987/R-1985-03-0603
■ Reaction of 4-Bromoalkyl-4-methoxy-2,5-oxazolidione with Alcohol or α-Amino Acid Ester and Transformation of the Products
Chung-gi Shin,* Naoyuki Takamatsu, Yoshiaki Sato, and Yasuchika Yonezawa
*Departmnet of Applied Chemistry, Faculty of Engineering, Kanagawa University, 3-27-1 Rokkakubashi, Kanagawa-ku, Yokohama 221-8686, Japan
Abstract
Reaction of N-carboxy α-dehydroamino acid anhydride with methanol in the presence of NBS gave 4-bromoalkyl-4-methoxy-2,5-oxazolidione, which was further treated with alcohol or α-amino acid ester to give extremely different two types of products, 2-oxazolinone and α-(oximino)acyl-α-amino acid derivatives respectively.
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