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Report | Regular issue | Vol 23, No. 2, 1985, pp.339-343
Published online, 1st January, 1970
DOI: 10.3987/R-1985-02-0339
Noncarbonylsiiron-induced Reaction of 2-Oxo-3-azabicyclo[3.2.0]hepta-3,.6-diene System. Preparation and Thermal Behavior of the Cyclobutene-iron Complex

Makoto Nitta* and Tomoshige Kobayashi

*Department of Chemistry, School of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan


The reaction of 4-phenyl-2-oxa-3-azabicyclo[3.2.0]hepta-3,6-diene with [Fe2 (CO) 9] afforded tetracarbonyl(h2-4-phenyl-2-oxa-3-azabicyclo[3.2.0]hepta-3,6-diene)iron along with 2-phenylpyridine. Thermal behavior of the complex and the reaction of the related compounds with [Fe2 (CO)9] giving pyridine derivatives were also studied.