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Report | Regular issue | Vol 22, No. 11, 1984, pp.2547-2552
Published online, 1st January, 1970
DOI: 10.3987/R-1984-11-2547
Phospholipid-like Porphinato Iron and Zinc Complexes: Synthesis and Properties

Yoh-ichi Matsushita, Etsuo Hasegawa, Kiyoshi Eshima, and Eishun Tsuchida*

*School of Science and Engineering, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan

Abstract

A new amphiphilic porphyrin having one hydrophilic group, 5,10,15-tri(α, α, α-o-pivalamidophenyl)-20-mono{α-o-[12-(2’-trimethylammonioethoxy)phosphinatoxy-2,2-dimethyldodecanamido]phenyl}porphine, and its zinc and iron complexes were prepared. These were efficiently embedded in a micelle or a liposome because of their amphiphilicity.