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Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Communication | Regular issue | Vol 22, No. 11, 1984, pp.2491-2494
Published online, 1st January, 1970■ Synthesis of Debromo-8,8a-dihydroflustramine C. A Model Experiment Related to the Total Synthesis of Amauromine
Published online, 1st January, 1970
DOI: 10.3987/R-1984-11-2491
■ Synthesis of Debromo-8,8a-dihydroflustramine C. A Model Experiment Related to the Total Synthesis of Amauromine
Shigehiro Takase,* Itsuo Uchida, Hirokazu Tanaka, and Hatsuo Aoki
*Fujisawa Pharmaceutical Co. Ltd., 2-1-6 Kashima, Yodogawa-ku, Osaka 532, Japan
Abstract
A derivative (1) from marine alkaloid, flustramine C, was synthesized utilizing thio-Claisen rearrangement at the key step. The method of the synthesis would be applied to synthesis of alkaloids possessing the reversed prenyl group at 3a position of hexahydropyrrolo[2,3-b]indole skeleton such as amauromine.
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