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Report | Regular issue | Vol 22, No. 9, 1984, pp.2029-2036
Published online, 1st January, 1970
DOI: 10.3987/R-1984-09-2029
High Valent Chromium Heterocyclic Complexes-II: New Selective and Mild Oxidants

Harry B. Davis, Roger M. Sheets, William W. Paudler, and Gary L. Gard*

*Department of Chemistry, Portland State University, Portland, Oregon 97207, U.S.A.


The new mild oxidizing agents, pyrazinium-N-oxide chlorochromate (PzOCC), tripyridinium hydrochloride chlorochromate (TPCC), and naphthyridinium dichromate (NapDC) have been prepared and characterized. A study of the oxidative behavior of these new compounds relative to pyridinium chlorochromate (PCC) and bipyridinium chlorochromate (BPCC) with selected primary and secondary alcohols is reported.