Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact: purchase@heterocycles.com

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Communication | Regular issue | Vol 22, No. 9, 1984, pp.1955-1958
Published online, 1st January, 1970
DOI: 10.3987/R-1984-09-1955
A Novel Ring-opening Reaction of Aziridine Induced by the Formation of Nitrogen-substituted Carbanion of Nonstabilized Type

Otohiko Tsuge,* Shuji Kanemasa, Hiroyuki Suga, and Koyo Matsuda

*Graduate School of Engineering, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan

Abstract

Desilylation of 1-(trimethylsilylmethyl)aziridines causes a novel ring-opening reaction of aziridine. Only aziridines whose ring bears at least one anion-stabilizing moiety undergo the desilylation, and the resultant carbanion of nonstabilized type changes into a stabilized one inviting the ring-opening. The types of products depend upon the number of anion-stabilizing moieties as well as the quenching reagents employed.