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Communication | Regular issue | Vol 22, No. 7, 1984, pp.1523-1526
Published online, 1st January, 1970
DOI: 10.3987/R-1984-07-1523
Synthesis and Ylidic Properties of 1-Arylthiabenzene 1-Oxides

Haruo Matsuyama,* Hiroyuki Takeuchi, and Yukio Okutsu

*Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan

Abstract

1-Arylthiabenzene 1-oxides were prepared by condensation reactions between arylmethyloxosulfonium methylides and 1,3-diphenyl-2-propyn-1-one (or 2-acetylcyclohexanone). An ylidelike bonding structure is proposed for the 1-arylthiabenzene 1-oxides.