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Report | Regular issue | Vol 22, No. 6, 1984, pp.1417-1420
Published online, 1st January, 1970
DOI: 10.3987/R-1984-06-1417
Consecutive Menschutkin Reaction of Cyclic Amines with Dichloromethane under High Pressure: Synthesis of Methylenebisamines

Kiyoshi Matsumoto,* Shiro Hashimoto, Yukio Ikemi, and Shinichi Otani

*Graduate School of Human and Environmental Studies, Kyoto University, Yoshida-Nihonmatsu-cho, Sakyo-ku, Kyoto 606-8501, Japan

Abstract

The reaction of heterocyclic amines such as pyrrolidine, piperidines, and morpholines with dichloromethane in methanol in the kiro bar region affording the corresponding methylenebisamines is described.