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Report | Regular issue | Vol 22, No. 2, 1984, pp.307-310
Published online, 1st January, 1970
DOI: 10.3987/R-1984-02-0307
The Stereoselective Oxidation of 1-Benzylnicotinium Bromide to Its 1‘-N-Oxide

Makoto Shibagaki,* Hajime Matsushita, and Hajime Kaneko

*Life Science Research Laboratory, Japan Tobacco Inc., 6-2, Umegaoka, Midori-ku, Yokohama, Kanagawa 227-8512, Japan


1’-N-oxidation of 1-benzylnicotinium bromide(4) was studied. Among the oxidizing agents examined, peroxomolybdate and peroxotungstate gave the cis- and trans-1’-N-oxides(5 and 6) in the ratio of 1 : 14 and 1 : 15, respectively.