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Communication | Regular issue | Vol 22, No. 1, 1984, pp.39-42
Published online, 1st January, 1970
DOI: 10.3987/R-1984-01-0039
The Effect of Triethylborane in the Reduction of Epoxides with Lithium Borohydride

Nung Min Yoon,* In Hwan Oh, Kyung Ill Choi, and Hoon Ju Lee

*Department of Chemistry, Sogang University, Mapoku, Seoul 121-742, Korea

Abstract

The presence of triethylborane dramatically accelerated the reduction of epoxides with lithium borohydride. Thus the all three epoxides tested, namely, 1,2-butylene oxide, cyclohexene oxide and styrene oxide were reduced rapidly in 1 h at room temperature in the presence of 25 mole % of triethylborane whereas more than 24 h was required for these reductions with lithium borohydride itself.