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■ Arene Syntheses by Extrusion of Heteroatoms from 7-Heteroatom-bicyclo[2.2.1]heptene Systems

Henry N. C. Wong, Tang-Kei Ng, and Tai-Yuen Wong

*Department of Chemistrym The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, Hong Kong

Abstract

Thermal and chemical extrusion of bridges containing O, S, N, P, Si, Ge, Sn, Co, Ir and Rh from the 7-heteroatom-bicyclo[2.2.1]heptenes are potentially important methods for constructing arenes with appropiate substituents.