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Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Communication | Regular issue | Vol 19, No. 10, 1982, pp.1823-1828
Published online, 1st January, 1970■ Synthesis of Some Oxazolin-5-one-4-spiro-1’-cyclopropanes Having Functional Groups and Their Thermal Rearrangements
Published online, 1st January, 1970
DOI: 10.3987/R-1982-10-1823
■ Synthesis of Some Oxazolin-5-one-4-spiro-1’-cyclopropanes Having Functional Groups and Their Thermal Rearrangements
Otohiko Tsuge, Michihiko Noguchi, and Hiroyuki Moriyama
*Research Institute of Industrial Science, Faculty of Engineering, Kyushu University, 6-1, Kasuga-koen, Kasuga 816-8580, Japan
Abstract
4-Cycloalkylidene-2-phenyl-2-oxazolin-5-ones reacted with carbonyl-stabilized sulfur methylides to give the corresponding dispiro compounds, which on heating were converted into retro-ene reaction products. The reaction of 4-cinnamylidene-2-phenyl-2-oxazolin-5-one with sulfur allylides afforded the Cope rearrangement products, accompanied by a spiro-cis-divinylcyclopropane in a certain case.
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