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Communication | Regular issue | Vol 16, No. 12, 1981, pp.2125-2131
Published online, 1st January, 1970
DOI: 10.3987/R-1981-12-2125
Chemistry of 1,6-Diazaphenalene. Halogenation

Shieu-Jeing Lee and James M. Cook*

*Department of Chemistry, University of Wisconsin-Milwaukee, Milwaukee, Wisconsin 53201, U.S.A.


The reaction of neutral species, 1,6-diazaphenalene, with halogen provided principally 2,3-dihalo- and 2,3,4-trihalodizaphenalenes in addition to lesser quantities of other isomers, whereas, halogenation of the protonated form 1b of 1,6-diazaphenalene gave a 7-substituted diazaphenalene as the major product.