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Communication | Regular issue | Vol 16, No. 8, 1981, pp.1287-1290
Published online, 1st January, 1970
DOI: 10.3987/R-1981-08-1287
High-pressure Diels-Alder Reactions of Furans with α-Chloro- and α-Acetoxyacrylonitrile

Hiyoshizo Kotsuki* and Hitoshi Nishizawa

*Department of Material Science, Faculty of Science, Kochi University, 2-5-1, Akebono-cho, Kochi 780-8520, Japan


The Diels-Alder reactions of furans with α-chloro- and α-acetoxyacrylonitrile very nicely proceeded under the conditions of 15 kbar and 30°C in dichloromethane. The adducts were proved to be a useful precursor for the synthesis of 7-oxa-bicyclo[2.2.1]heptanone derivatives.