Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact: purchase@heterocycles.com

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Communication | Regular issue | Vol 16, No. 8, 1981, pp.1287-1290
Published online, 1st January, 1970
DOI: 10.3987/R-1981-08-1287
High-pressure Diels-Alder Reactions of Furans with α-Chloro- and α-Acetoxyacrylonitrile

Hiyoshizo Kotsuki* and Hitoshi Nishizawa

*Department of Material Science, Faculty of Science, Kochi University, 2-5-1, Akebono-cho, Kochi 780-8520, Japan

Abstract

The Diels-Alder reactions of furans with α-chloro- and α-acetoxyacrylonitrile very nicely proceeded under the conditions of 15 kbar and 30°C in dichloromethane. The adducts were proved to be a useful precursor for the synthesis of 7-oxa-bicyclo[2.2.1]heptanone derivatives.