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Communication | Regular issue | Vol 16, No. 7, 1981, pp.1141-1143
Published online, 1st January, 1970
DOI: 10.3987/R-1981-07-1141
Reductive Photocyclization of Enamide in the Presence of a Chiral Metal Hydride Complex — Asymmetric Synthesis of Xylopinine

Takeaki Naito, Yukiko Tada, and Ichiya Ninomiya*

*Kobe Women’s College of Pharmacy, Motoyamakita, Higashinad, kobe, Hyogo658, Japan

Abstract

Total synthesis of optically active xylopinine (3b) was achieved by reductive photocyclization of enamide (1) in the presence of a chiral hydride complex.