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Communication | Regular issue | Vol 14, No. 10, 1980, pp.1455-1456
Published online, 1st January, 1970
DOI: 10.3987/R-1980-10-1455
A Novel Synthesis of (±)-Fumaricine

Miyoji Hanaoka,* Shingo Yasuda, Yuriko Hirai, Kazuyoshi Nagami, and Takeshi Imanishi

*Faculty of Pharmaceutical Scicences, Kanazawa University, 13-1 Takara-machi, Kanazawa 920-0934, Japan


A novel synthesis of (±)-fumaricine (9) from the phenolbetaine (5) via the 8,14-cycloberbine (6), the photochemical valence tautomer of 5, is described.