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Communication | Regular issue | Vol 12, No. 12, 1979, pp.1529-1533
Published online, 1st January, 1970
DOI: 10.3987/R-1979-12-1529
The Photoreaction of Morusin Trimethyl Ether

Taro Nomura,* Toshio Fukai, and Masako Amagai

*School of Pharmaceutical Sciences, Toho University, 2-2-1, Miyama, Funabashi, Chiba 274-8510, Japan

Abstract

The photoreaction of morusin trimethyl ether (Ia) afforded hydroperoxide (II), the structure of which was confirmed on the basis of spectral and chemical data. On the other hand, the photoreaction of morusin-2’,4’-dimethyl ether (Ib) did not occur. The possible mechanism of the photoreaction of Ia is discussed being based on the several experimental results obtained here.