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Communication | Regular issue | Vol 12, No. 10, 1979, pp.1275-1279
Published online, 1st January, 1970
DOI: 10.3987/R-1979-10-1275
Configurational and Chemical Studies on (—)-6,8-Dibromobornane-2-one

Shin-ichi Nagai, Noriichi Oda, and Isoo Ito*

*Faculty of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Mizuho-ku, Nagoya 467-8603, Japan

Abstract

The absolute configuration of C6-bromine in (-)-6,8-dibromobornane-2-one (2) was confirmed by the spectral data. Condensation of 2 with hydrazine hydrate gave diazatricyclo[4,4,0,05,9]dec-7-one (7) which provided Diels-Alder adducts (9a,b) with dienes.