Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact:

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Communication | Regular issue | Vol 4, No. 5, 1976, pp.933-938
Published online, 1st January, 1970
DOI: 10.3987/R-1976-05-0933
A Study of the Reaction between 1-Halogenobenzyl-2-benzazepines and Dimsylsodium

Shinzo Kano,* Tsutomu Yokomatsu, and Shiroshi Shibuya

*School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan


The reaction between a series of 1-(2-bromobenzyl)-1,2,3,4-tetrahydro-5H-2-benzazepines (1), (2), (3) and dimsylsodium was examined to give 5,6,7,8-tetrahydrodibenz[b,f]azecines possessing a cis and trans double bond at the 13,14-position together with formation of 14-(methylsulfinyl)methyldibenz[b,f]azecine derivatives.