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Communication | Regular issue | Vol 4, No. 1, 1976, pp.1-7
Published online, 1st January, 1970
DOI: 10.3987/R-1976-01-0001
Intramolecular 1,3-Dipolar Cycloadditions of Arynyl Azides on Alkyl and Alkenyl Groups

Otohiko Tsuge,* Kazunori Ueno, and Akitaka Inaba

*Research Institute of Industrial Science, Faculty of Engineering, Kyushu University, 6-1, Kasuga-koen, Kasuga 816-8580, Japan


Aryl azides 2 containing alkynyl or alkenyl group as dipolarophile were prepared and thermally decomposed in benzene. Azides 2a-3d gave the corresponding 1,3-cycloadducts, fused-ring l,2,3-triazoles 8a-8d, while bridgehead nitrogen aziridines 9 and 10, were obtained from 3e and 3f, probably via unstable δ2-1,2,3-triazolines.