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Communication | Regular issue | Vol 3, No. 9, 1975, pp.719-722
Published online, 1st January, 1970
DOI: 10.3987/R-1975-09-0719
Photoaddition Reactions of N-Methylphthalimide with Toluenes and Amines

Yuichi Kanaoka,* Kazuko Sakai, Ryuji Murata, and Yasumaru Hatanaka

*Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan


Photoreactions of N-methylphthalimide 1 were examined in presence of substituted toluenes and tertiary amines. Together with the reduced products 3, 5, 6, the addition products 2, 4, were obtained. It has been shown that the imide carbonyl is capable of photochemically adding the methylene adjacent to benzene and nitrogen.