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Communication | Regular issue | Vol 3, No. 5, 1975, pp.363-366
Published online, 1st January, 1970
DOI: 10.3987/R-1975-05-0363
The Barrier to Ring Reversal in Some 5,5-Disubstituted 1,2,3-Trithianes

Gustaaf Goor and Marc Anteunis*

*Laboratory for NMR Spectroscopy, Department of Chemistry, State University of Gent, Krijgslaan 271 (S.4bis), B-9000 Gent, Belgium

Abstract

Barriers for ring inversion have been measured in a series of 5,5-disubstituted 1,2,3-trithianes. As expected, these derivatives inverse slower than the parent unsubstituted compound, except for 5-CH2R (R = Me, i.Pr) substituents.