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■ Stereoselective Synthesis of 1,4-Dideoxy-1,4-imino-L-lyxitol and 1,5-Dideoxy-1,5-imino-D-ribitol

Ki Chang Jang, Ill-Yun Jeong, Min Suk Yang, Sang Uk Choi, and Ki Hun Park*

*Department of Agricultural Chemistry, Gyeongsang National University, Chinju, 660-701, Korea

Abstract

1,4-Dideoxy-1,4-imino-L-lyxitol (2) and 1,5-dideoxy-1,5-imino-D-ribitol (3) were prepared from allylic alcohol (1) derived from D-glucono-δ-lactone. Key transformation includes diastereoselective epoxidation of (1) with m-CPBA.