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Communication | Regular issue | Vol 53, No. 3, 2000, pp.535-538
Published online, 1st January, 1970
DOI: 10.3987/COM-99-8800
Crystal Structures of Mercury(II) Dichloride Complexes of 5,8-Dioxa-2,11-dithiabicyclo[10.4.1]heptadeca-1(16),12,14-trien-17-one and 5,8,11-Trioxa-2,14-dithiabicyclo[13.4.1]icosa-1(19),15,17-trien-20-one

Kanji Kubo,* Nobuo Kato, Akira Mori,* and Hitoshi Takeshita

*Institute of Advanced Material Study, 86, Kyushu University, Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan


5,8-Dioxa-2,11-dithiabicyclo[10.4.1]heptadeca-1(16),12,14-trien-17-one (1b) and 5,8,11-trioxa-2,14-dithiabicyclo[13.4.1]icosa-1(19),15,17-trien-20-one (1c) formed 1b-2HgCl2 and 1c-2.5HgCl2-H2O complex with HgCl2 and H2O, respectively. The Hg(II) ions were coordinated to both the tropone carbonyl group and the thioether sulfur atom to form a side-on complex.