Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact:

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Communication | Special issue | Vol 49, No. 1, 1998, pp.67-71
Published online, 1st January, 1970
DOI: 10.3987/COM-98-S32
Allylation of N-Acyl Quaternary Salts of Azaaromatics with Allyltrimethylsilane in the Presence of Triflate Ion

Takashi Itoh, Michiko Miyazaki, Kazuhiro Nagata, and Akio Ohsawa*

*School of Pharmaceutical Sciences, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo 142-8555, Japan


Imidazoles and thiazoles were allowed to react with allyltrimethylsilane in the presence of chloroformate and triflate ion to give N-acyl 2-allyl adducts in good yields. The same reaction was also proceeded in the cases of pyridazines and phthalazine as substrates.