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Communication | Special issue | Vol 46, No. 1, 1997, pp.49-52
Published online, 1st January, 1970
DOI: 10.3987/COM-97-S20
Fusion of C60 with Cyclic Amino Acid and Thiourea by Hetero Diels-Alder Reactions

Masatomi Ohno, Satoshi Kojima, Yuri Shirakawa, and Shoji Eguchi*

*Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, Aichi 464-8601, Japan

Abstract

C60 underwent hetero Diels-Alder reaction with a carbethoxysubstituted 2-aza-1,3-butadiene and trimethylsilylthio-substituted 1,3-diaza-1,3-butadiene (which possibly reacts as trimethylsilylamino-substituted 1-thia-3-aza-1,3-butadiene) to give C60 derivatives fused with cyclic amino acid and thiourea, respectively. The latter was explained to arise under equilibrated conditions.