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Communication | Special issue | Vol 47, No. 1, 1998, pp.91-96
Published online, 1st January, 1970
DOI: 10.3987/COM-97-S(N)29
Synthetic Study of Neocarzinostatin Chromophore: Stereoselective Synthesis of N-Methylfucosamine and Its α-Glycoside

Toshio Kaneko, Kazunobu Takahashi, and Masahiro Hirama*

*Department of Chemistry, Graduate School of Science, Tohoku University, Aobayama, Sendai 980-8578, Japan

Abstract

Stereoselective glycosylation of cyclopentanol with 2-azido-2,6-dideoxygalactopyranose (2-azidofucose) derivatives and its transformation to N-methylfucosamine was achieved as a model for the synthesis of neocarzinostatin chromophore.