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Paper | Regular issue | Vol 48, No. 3, 1998, pp.461-464
Published online, 1st January, 1970
DOI: 10.3987/COM-97-8057
Silver(I) Ion-mediated Desulfurization-Condensation of Carbon Disulfide with Some Hydroxyl Compounds

Isao Shibuya,* Yasuo Gama, and Masao Shimizu

*National Institute of Materials and Chemical Research, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan


The title reaction with ethanol and phenol gave tetraethyl and tetraphenyl orthocarbonate, respectively, in good yields. Diols, such as benzene-1,2-dimethanol, meso-hydrobenzoin, and cathecol, afforded spiro orthocarbonic acid esters. In the same manner, 2-anilinoethanol, N-methylanthranilic acid, and salicylic acid led to some novel spirobicyclces.