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Obituary
Zenichi Yoshida (1925-2023)
Zenichi Yoshida (1925-2023)
Professor. Zenichi Yoshida,
a member of the Honorary Advisors of HETEROCYCLES (1975-1998),
has passed away on May 4, 2023 at the age of 97.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
May 11, 2023
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Note | Regular issue | Vol 45, No. 10, 1997, pp.2007-2013
Published online, 1st January, 1970■ Synthesis of Vinca Alkaloids and Related Compounds LXXXVIII. Highly Enantioselective Synthesis of (+)-Vincamine
Published online, 1st January, 1970
DOI: 10.3987/COM-97-7884
■ Synthesis of Vinca Alkaloids and Related Compounds LXXXVIII. Highly Enantioselective Synthesis of (+)-Vincamine
Tamás Nagy, Lajos Szabó, György Kalaus, and Csaba Szántay*
*Institute for Organic Chemistry, Technical University Budapest, H-1521 Budapest, P.O. Box 91Gellért tér 4, Hungary
Abstract
The interaction of the chiral malonic ester derivative (5) with formaldehyde and Wenkert enamine (1) yields the tetrahydropyranoindoloquinolizine (6), from which a highly enantioselective synthesis of the commercially important alkaloid (+)-vincamine (12) was achieved.
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