Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact: purchase@heterocycles.com

Price: ¥ 4,400 (Yen only)
Period: This Article can be accessed for 7 days.

Paper | Regular issue | Vol 45, No. 6, 1997, pp.1081-1095
Published online, 1st January, 1970
DOI: 10.3987/COM-97-7753
Synthesis and Structural Investigation of Some Cyclic Ketene Acetals. Detection of an Unexpected Proton Transfer in (3-Benzylthiazolidin-2-ylidene)acetamide

Csaba Szántay Jr.,* István Szabadkai, Kálmán Harsányi, and Ferenc Trischler

*Chemical Works of Gedeon Richter Ltd., Spectroscopic Research Division, Budapest 10, P. O. Box 27, H-1475 Budapest, Hungary

Abstract

The thiazolidines (2) and (3) were synthesized. Some of these compounds exhibit unexpected chemical behavior; e.g in the case of (3-benzylthiozolidin-2-ylidene)acetamide (3b), NMR investigations revealed the presence of chemical exchange involving C(6)-H and the NH2 protons.