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Paper | Regular issue | Vol 45, No. 2, 1997, pp.277-286
Published online, 1st January, 1970
DOI: 10.3987/COM-96-7650
Addition of 2-Trimethylsilyloxyfuran to Catalytically Generated N-Methyleneamine Equivalents: Synthesis of 5-Aminomethyl-2,5-dihydrofuran-2-ones

Hyun-Joon Ha,* Kyung-Ho Kang, Young-Gil Ahn, and Seung-Jun Oh

*Department of Chemistry, Hankuk University of Foreign Studies, Yongin, Kyunggi-Do, 449-791, Korea


Catalytically generated N-methyleneamine equivalents from N-methoxymethylanilines, 1,3,5-triphenyl- and 1,3,5-tribenzylhexahydro-1,3,5-triazines in the presence of Lewis acid reacted with 2-trimethylsilyloxyfuran to give 5-aminomethyl-2,5-dihydrofuran-2-ones in high yield.