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Communication | Regular issue | Vol 43, No. 11, 1996, pp.2337-2342
Published online, 1st January, 1970
DOI: 10.3987/COM-96-7594
Stereoselective Synthesis of 6α-Halopenicillanates by Samarium(II) Iodide-promoted Reduction of 6,6-Dihalopenicillanates

Han-Young Kang, Ae Nim Pae, Yong Seo Cho, Kyung II Choi, Hun Yeong Koh, and Bong Young Chung

*Department of Chemistry, Chonbuk National University, Dukjindong 664-14, Chonju, 561-756, Korea


A mild and efficient samarium(II) iodide promoted-reduction of 6,6-dibromopenicillanates for stereoselective synthesis of 6α-bromopenicillanates has been developed.