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Paper | Regular issue | Vol 43, No. 11, 1996, pp.2435-2441
Published online, 1st January, 1970
DOI: 10.3987/COM-96-7567
Synthesis of 3-Alkyl-4-aryl- and 3,4-Diaryl-1,2,5-thiadiazoles via Palladium-catalyzed Cross-Coupling Reaction

Yasuaki Hanasaki

*Tokyo Research Laboratory, Tosoh Corporation, 2743-1, Hayakawa, Ayase-shi, Kanagawa-ken 252, Japan

Abstract

4-Substituted 3-aryl-1,2,5-thiadiazoles were synthesized by palladium-catalyzed cross-coupling reaction of aryldtannane with easily available 4-substituted 3-halogeno- and 3-trifluoromethylsulfonyloxy-1,2,5-thiadiazoles.