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Communication | Regular issue | Vol 43, No. 6, 1996, pp.1159-1163
Published online, 1st January, 1970
DOI: 10.3987/COM-96-7430
X-Ray Structures of a Pair of Atropisomers of 1-Acyl-2-arylindolines. Remarkable Through-Space Aryl-Aryl Interaction

Masashi Eto, Fumikazu Ito, Takeo Kitamura, and Kazunobu Harano*

*Faculty of Pharmaceutical Sciences, Kumamoto University, 5-1 Oe-hon-machi, Kumamoto 862, Japan

Abstract

A pair of atropisomers due to restricted rotation about Dsp3-Csp2 bond for 1-(4’-nitrobenzoyl)-2-(2"-hydroxynaphthyl)-3,3-dimethylindoline was isolated. The crystal structures of a pairs of the atropisomers indicate the presence of a significant through-space interaction between the aryl moieties.