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Communication | Special issue | Vol 42, No. 1, 1996, pp.159-164
Published online, 1st January, 1970
DOI: 10.3987/COM-95-S64
Total Synthesis of Mycalamide A. Further Synthetic Study of the Right Half

Tadashi Nakata, Hideto Fukui, Tadakiyo Nakagawa, and Hiroko Matsukura

*The Institute of Physical and Chemical Research, Wako-shi, Saitama 351-0198, Japan


The right half 5 of mycalamide A (1) was synthesized starting from (R)- or (S)-pantolactone via the Sharpless asymmetric dihydroxylation as the key step. The total synthesis of mycalamide A (1) was accomplished by coupling of the right and left halves.