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Obituary
Yoshito Kishi (1937-2023)
Yoshito Kishi (1937-2023)
Professor. Yoshito Kishi,
a member of the Honorary Editorial Associates of HETEROCYCLES,
has passed away on January 9, 2023 at the age of 85.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
January 13, 2023
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Paper | Regular issue | Vol 43, No. 3, 1996, pp.601-610
Published online, 1st January, 1970■ An Alternative Method for Lactonization of β,γ-Enoic Acids and its Application to Verticillene-10-carboxylic Acid
Published online, 1st January, 1970
DOI: 10.3987/COM-95-7320
■ An Alternative Method for Lactonization of β,γ-Enoic Acids and its Application to Verticillene-10-carboxylic Acid
Yoshihiro Yaguchi, Mitsuhiro Akiba, Makoto Harada, and Tadahiro Kato*
*Department of Chemistry, Faculty of Science, Science University of Tokyo, Kagurazaka 1-3, Shinjuku-ku, Tokyo 162, Japan
Abstract
The reaction with iodine in refluxing acetic acid was found to be an alternative method for the lactonization of β,γ-enoic acids. Application of the method to verticillene-10-carboxylic acid (6) resulted in the formation of three γ-lactones (7, 12, and 13), 12 being an unexpected product.
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