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Paper | Regular issue | Vol 43, No. 2, 1996, pp.471-474
Published online, 1st January, 1970
DOI: 10.3987/COM-95-7318
Studies on Isocyanides. 2-Isocyanothioanisole, a Synthetic Equivalent of the Benzothiazol-2-yl Anion

Ricardo Bossio, Stefano Marcaccini,* Roberto Pepino, and Tomás Torroba

*CNR, Centro di Studio sulla Chimica e la Struttura dei Composti Eterociclici e loro Applicazioni, Dipartimento di Chimica Organica "Ugo Schiff", Università di Firenze, via Gino Capponi 9, I-50121 Firenze, Italy

Abstract

A synthesis of 2-isocyanothioanisole (3) is described. The reaction between 3 and electrophilic reagents took place easily to give 2-functionalized benzothiazoles (6).