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Communication | Special issue | Vol 40, No. 2, 1995, pp.511-514
Published online, 1st January, 1970
DOI: 10.3987/COM-94-S59
Thermal Reactions of 2-Cyclopropyl-2H-azirines

Kazuaki Isomura, Hideshi Kawasaki, Kenji Takehara, and Hiroshi Taniguchi

*Department of Chemical Engineering, Kitakyushu National College of Technology, Shii, Kokuraminami-ku, Kitakyushu 803, Japan


Thermal rearrangement of 2H-azirines having a cyclopropane ring was revealed to give pyridines. Ene reaction involving a C=N bond to form tricyclic compound was observed in the case of 2-cyclopropyl-2H-azirine having an isobutenyl group cis to the azirine ring, whereas the trans isomer gave a pyridine ring exclusively.