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Paper | Special issue | Vol 39, No. 2, 1994, pp.657-667
Published online, 1st January, 1970
DOI: 10.3987/COM-94-S(B)58
Synthetic Approaches towards Mitomycins: Synthesis of the Decarbamoyloxymitomycin Derivative

Yoshio Ban,* Shigekazu Nakajima, Kiyoshi Yoshida, Miwako Mori, Masakatsu Shibazaki,* and Tadamasa Date

*Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan


The benzazocine derivative (2) obtained by the criss-cross annulation reaction has been successfully converted to the decarbamoyloxymitomycin derivative (1) in a highly regio and stereocontrolled manner.