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Communication | Regular issue | Vol 41, No. 3, 1995, pp.415-418
Published online, 1st January, 1970
DOI: 10.3987/COM-94-6986
Asymmetric Synthesis of Celacinnine Utilizing Optically Active Vinyl Sulfoxides

Nobuhiro Itoh, Haruo Matsuyama*, Masao Yoshida, Nobumasa Kamigata, and Masahiko Iyoda*

*Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-03, Japan


First asymmetric synthesis of celacinnine (10) was achieved from the nine-membered azalactam, 3-phenyl-4-azaoctanelactam (6), which was synthesized by the addition of piperidazine (4) to optically active vinyl sulfoxides (3).