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Communication | Regular issue | Vol 38, No. 10, 1994, pp.2153-2158
Published online, 1st January, 1970
DOI: 10.3987/COM-94-6802
Synthesis and Properties of Tetrathiafulvalene Derivatives Containing Quinoid Structures: Novel Electron Donors of Organic Conductors

Katsuhiro Saito,* Chikayuki Sugiura, Emi Tanimoto, Katsushi Saito, and Yoshiro Yamashita

*Faculty of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan

Abstract

Wittig-Horner reactions of 2-dimethoxyphosphinyl-1,3-dithiole derivatives with a benzoquinone-cyclopentadiene adduct and anthraquinone afforded new types of electron donors with alkylthio groups for organic conductors which showed reversible oxidation waves on cyclic voltammetries and formed conductive charge-transfer complexes with TCNQ or DDQ.