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Paper | Regular issue | Vol 38, No. 6, 1994, pp.1339-1346
Published online, 1st January, 1970
DOI: 10.3987/COM-94-6689
Electrogeneration and Structural Discussion of 6-Benzyl-3,5-diphenylhydroxypyranones

Jose I. Lozano and Fructuoso Barba*

*Departamento de Química Orgánica, Universidad de Alcalá de Henares, 28871 Alcalá de Henares (Madrid), Spain

Abstract

The cathodic reduction of 2-chloro-2-phenylacetyl chloride in dichloromethanetetraethylammonium chloride on mercury cathode led to the formation of either a mixture of α- and γ-6-benzyl-3,5-diphenylhydroxypyranones or corresponding phenylacetate derivative of the latter depending on the conditions, in only one step. A study of these compounds solved the controversy which existed in the literature about the correct assignment of these structures.