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Communication | Special issue | Vol 37, No. 3, 1994, pp.1451-1454
Published online, 1st January, 1970
DOI: 10.3987/COM-93-S88
Synthesis of Chiral Lactams as Templates for Enzyme Inhibitors: An Unusual Annulation in the Intramolecular Wadsworth-Horner-Emmons Reaction

Ramaswamy Shankar and A. Ian Scott*

*Center for Biological NMR, Department of Chemistry, Texas A & M University, College Station, Texas 77843-3255, U.S.A.

Abstract

Intramolecular carbonylolefination of a dipeptide keto phosphonate furnished unexpected lactams through rearrangement of the phosphonate carbanion.