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Communication | Special issue | Vol 37, No. 1, 1994, pp.187-191
Published online, 1st January, 1970
DOI: 10.3987/COM-93-S24
Thionium Ion-activated Pinacol Rearrangements. Generality and Scope

Leo. A. Paquette,* Uta Dullweber, and Bruce M. Branan

*Evans Chemical Laboratories, The Ohio State University, 120 W. 18th Avenue, Columbus, Ohio 43210, U.S.A.

Abstract

The acid-catalyzed rearrangement of tertialy allylic alcohols produced by the addition of 5-lithio-2,3-dihydrothiophene to cyclic ketones of various ring size has been probed.